The rapid development of the modern mobile communication technology has led to an urgent demand for miniaturized and lightweight fabrication of microwave circuitry and systems [1]. Low-temperature co-fired ceramics (LTCC) technology can facilitate the miniaturization of these devices by simultaneously decreasing the dielectric layer thickness and increasing the number of layers in multi-layered structures. Micrometer-scale dielectric layers generally require 20–30 layers of particles to be longitudinally stacked together to ensure their homogeneity and smoothness, which requires the use of nanometer-scale grains in ceramics fabrication [2]