Multipath due to reflections of the sea surface, seabed, and obstacles, as well as inhomogeneity within the ocean, is an important characteristic of underwater acoustic channels. Mutual interference among multiple paths causes severe amplitude fading and frequency selective fading. The guard interval is an effective anti-multipath method, but an excessively long guard interval will reduce the data rate of multicarrier underwater acoustic communication. In this paper, we propose a new anti-multipath multi-carrier communication method based on orthogonal chirp division multiplexing (OCDM) that uses chirp signals for carrier modulation. As OCDM exploits the multipath components for diversity gain, the system robustness is improved. The new method also adds a data pick-based rake receiver for maintaining good communication performance, even at short guard intervals. We detail the implementation and parameter selection of the antimultipath OCDM system and compare its performance with the traditional orthogonal frequency division multiplexing (OFDM) scheme using simulations; under a severe multipath simulation condition (the delay spread is longer than the guard interval), the anti-multipath OCDM achieves a bit error rate (BER) of 10 -6 , while the OFDM has a BER floor of 10 -3 . The simulation results verify the feasibility of the proposed method and the superiority of its anti-multipath performance.