Herein, arginine, and Triton X-100 was added to the washing liquid based on FA / O II in order to remove the effect of the change in concentration of BTA studies (three chemical substances as the primary surfactant and complexing agent molecular structure shown in Figure 1). Compared with other methods described above, we use the low price of chemicals, non-volatility, low toxicity and environmental protection, more suitable for large-scale use of the industrial sector. In detail, FA / O II having 13 or more chelate rings, it can react to form a stable chelate with copper ions, although the organic amines polyhydroxy macromolecule, but will not evaporate due to the high vapor pressure into the environment thereby causing deterioration in the photolithography process [17]. Arginine is a basic amino acid, containing amino and carboxyl functional groups may be combined to promote the complex copper ions to prevent the redeposition of [23-24]. Triton X-100 is a nonionic surfactant having a low surface tension and good wettability, during the cleaning process do not introduce ionic contaminants [25-26]. In our experiments, the contact angle and electrochemical methods are used to characterize the removed portion is calculated while BTA quantum mechanics parameters arginine, then we use the atomic force microscopy (AFM) analysis of the morphology of the copper surface after cleaning.
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