图5.7为不同超重力因子β对MnO2/PPy复合电极材料比容量的影响。

5.7 Effect of FIG different gravity factors β of MnO2 / PPy composite electrode material specific capacity. The reaction conditions were: p-TSA at a concentration of 0.84 mol L-1, u is the initial velocity impingement 9.43 m • s-1, KMnO4 concentration of 0.094 mol L-1, the reaction time was 3.5 h. As can be seen from the figure, at different current densities, MnO2 / PPy β increases with increasing specific capacity is increased to a certain degree, both the specific capacity starts to decrease. This may be explained from the stabilization mechanism monomer droplets, oil, aqueous two-phase emulsion requires a certain energy input, so that the filler beta] increases the line speed increases, the shear strength of the emulsion is significantly enhanced, thereby forming a nanoscale fine droplets, fine emulsion emulsifier droplets can be sufficiently adsorbed on the surface to prevent droplets Aositewa de aged between occurrence of the phenomenon; when β over 65.32, speed continues to increase causes further reduction of droplet size, liquid dropwise such that the specific surface area increases increasing surface tension, the surface of the emulsion droplets is insufficient to maintain stable monomer droplets, small droplets to accelerate the rate of migration of large droplets, coupled with the intense mixing crash severity, thereby resulting in a stable miniemulsion decreased, the impact on MnO2 / PPy composite structure, which is also specific capacity decreases.

Figure 5.7 shows the effect of different overweight factor beta on the ratio capacity of MnO2/PPy composite electrode materials. The reaction conditions are: p-TSA concentration of 0.84 mol L-1, impact speed u is 9.43 m?s-1, KMnO4 concentration is 0.094 mol L-1, reaction time is 3.5 h. As can be seen from the figure, the MnO2/PPy ratio capacity increases with the increase of beta at different current densities, and when it increases to a certain extent, the ratio decreases. This can be explained from the stabilization mechanism of monomer droplets, oil, water two-phase emulsification requires a certain amount of energy input, beta increase makes the filler line speed increase, the shearing force of the emulsion significantly enhanced, thus forming a nano-scale fine droplets, fine emulsion system emulsifier can be fully adsorbed on the surface of small droplets, to prevent the occurrence of ostwald maturation between droplets And, when beta exceeds 65.32, the continued increase in speed will cause the droplet size to further decrease, the increase of droplet ratio surface area makes the surface tension increase, the emulsifier on the surface of the single droplet is not enough to maintain the stability of the droplet, the small droplet to the large droplet migration rate is accelerated, coupled with the high degree of mixing collision, resulting in the stability of the fine emulsion, the impact on the structure of MnO2/PyP composite material, the impact on the ratio is also reduced.

Figure 5.7 shows the effect of different hypergravity factor β on the specific capacity of MnO2 / PPy composite electrode material. The reaction conditions are as follows: the concentration of p-tsa is 0.84 mol L-1, the initial velocity of impact u is 9.43 m · s-1, the concentration of KMnO4 is 0.094 mol L-1, and the reaction time is 3.5 h. It can be seen from the figure that under different current densities, the specific capacity of MnO2 / PPy increases with the increase of β, and when it increases to a certain extent, the specific capacity starts to decrease. This can be explained by the mechanism of monomer droplet stabilization. Oil and water two phase emulsification requires a certain amount of energy input. The increase of filler rate makes the filler line speed increase, and the shear strength of emulsion increases significantly, resulting in the formation of nanoscale droplets. In the miniemulsion system, the emulsifier can be adsorbed on the surface of small droplets sufficiently, preventing the occurrence of Ostwald ripening phenomenon between droplets. After 65.32 times, the continuous increase of rotational speed will lead to a further decrease of droplet size. The increase of the surface area of the droplet increases the surface tension. The emulsifier on the surface of the monomer droplet is not enough to maintain the droplet stability, the droplet migration rate to the large droplet is accelerated, and the degree of mixed collision is intense, resulting in the decrease of the stability of miniemulsion, and the fabrication of MnO2/PPy composite structure. As a result, its specific capacity is also reduced.<br>