In this paper, phenol simulated wastewater was used as the research object, nano-Fe3O4 prepared by hydrothermal synthesis method was used as catalyst, air and hydrogen peroxide were used as oxidant, and the catalytic oxidation effect of phenol was studied. The structure was characterized by SEM, N adsorption/desorption and other methods, and the catalytic ozonation treatment phenol wastewater system was constructed, the catalytic conditions were optimized, the treatment efficiency was improved, and the catalytic mechanism and catalyst stability were discussed in depth. The research found that alone When hydrogen peroxide was used as oxidant or air alone was used as oxidant, the removal rate of phenol was not ideal, but when hydrogen peroxide was oxidized together with air, the removal rate of phenol was significantly increased. The experimental results show that the removal rate of phenol and COD are significantly accelerated with the increase of temperature and catalyst dosage, and the removal rate of phenol does not increase with the increase of hydrogen peroxide dosage, but there is an optimum value. Studies have shown that α-FeO exhibits excellent synergistic effect on ozonolysis, has good continuous removal capacity and structural stability of phenol, and can provide technical reference for efficient removal of phenol-containing wastewater or refractory wastewater.
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