Electrochemical conversion of NO3-

Electrochemical conversion of NO3- into ammonia (NH3) recycles nitrogen and offers a route to NH3 production that is more valuable than dinitrogen gas. However, today’s development of NO3- electroreduction remains hindered by the lack of a mechanistic picture of how catalyst structure may be tuned to enhance catalytic activity. Here we demonstrate enhanced nitrate reduction reaction (NO3-RR) performance on Cu50Ni50 alloy catalysts, including a 0.12 V upshift in the half-wave potential and a 6-fold increase in activity compared to pure Cu at 0 V vs. reversible hydrogen electrode (RHE). Ni alloying enables tuning of the Cu d-band center and modulates the adsorption energies of intermediates such as *NO3-, *NO2, and *NH2. Using density functional theory (DFT) calculations, we identify a NO3-RR-to-NH3 pathway and offer an adsorption energyactivity relationship for the CuNi alloy system. This correlation between catalyst electronic structure and NO3-RR activity offers a design platform for further development of NO3-RR catalysts.