The non-renewable fossil fuels are continuing to remain the dominant energy source in power plants and automobiles to satisfy the ever-growing energy demands. However, the combustion of fossil fuels mainly generates nitrogen oxide (NOx) pollutants (NO, NO2, and N2O and their derivatives) which can cause acid rain, photochemical smog, ozone depletion, and eutrophication problems [1–4]. Due to the negative impacts of NOx, the mitigation of NOx emissions is of paramount importance for environmental protection. Several technologies are available to reduce NOx emissions by using catalytic materials and among them, selective catalytic reduction of NOx with NH3 (NH3-SCR) has been widely applied due to its high NOx removal efficiency [5–7]. Usually, the flue gas temperature of the industrial process is as low as 300 ◦C and, thus, the SCR catalyst must be active in the low-temperature regime (100–300 ◦C). V2O5–WO3(MoO3)/TiO2 is the typical and efficient catalyst and has been commercialized for NH3-SCR technology for medium temperature process [8,9]. However, this catalyst has some intrinsic drawbacks such as narrow and high working temperature window (350–400 ◦C), and low N2 selectivity in the high-temperature range [3,10,11]. Therefore, many researchers continue to develop highly active catalysts for low-temperature NH3-SCR in a wide temperature window.
不可再生的化石燃料将继续留在发电厂和汽车的主要能源,以满足不断增长的能源需求。然而,化石燃料的燃烧主要产生氮氧化物(NOx)的污染物(NO,NO 2,和N 2 O和它们的衍生物),其可以引起酸雨,光化学烟雾,臭氧层破坏,和富营养化问题[1-4]。由于氮氧化物的负面影响,氮氧化物排放量的减排是环境保护至关重要。几个技术可通过使用催化材料和它们之间,以减少NOx排放,NOx的用NH 3(NH3-SCR)的选择性催化还原已经被广泛由于其高的NOx去除效率[5-7]施加。通常,所述工业过程的烟道气体温度低至300◦C,因此,SCR催化剂必须在低温度状态(100-300◦C)活性。V2O5-WO3氧化钼(MoO 3)/ TiO2的是典型的和有效的催化剂和已经商业化用于NH3-SCR技术用于中温过程[8,9]。然而,该催化剂具有一定的固有缺点,如窄和高的工作温度窗口(350-400◦C)和低N2选择性在高温度范围[3,10,11]。因此,许多研究人员继续开发低温NH3-SCR高活性催化剂在很宽的温度窗口。和低N 2选择性在高温度范围[3,10,11]。因此,许多研究人员继续开发低温NH3-SCR高活性催化剂在很宽的温度窗口。和低N 2选择性在高温度范围[3,10,11]。因此,许多研究人员继续开发低温NH3-SCR高活性催化剂在很宽的温度窗口。
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