There are several routes for syngas generation from any carbonaceous feedstock. All technologies used for synthesis gas technologies are based either on steam reforming, partial oxidation, or a combination of the two as in Autothermal Reformer (ATR) [1]. The preparation of synthesis gas is one of the most capital intensive parts of a GTL-complex and may account for 30% to 50% of the total investment including cryogenic Air Separation Unit (ASU). The main reason for this high estimate is the high cost of ASU. ATR has become the state-of-the-art synthesis gas production technology for Fischer-Tropsch applications [2]. ATR is a relatively simple piece of equipment with a burner and a catalyst bed in a brick-lined pressure vessel [3]. In almost all GTL plants that utilize ATR, oxygen is used as oxidant, as in Oryx GTL plant in Qatar. Oxygen-blown ATR has also been commercially used in methanol synthesis [4] and is the preferred technology for large-scale GTL plants