In the simultaneous
presence of boron dopants and nitrogen defects, the BH400
sample exhibits further enhanced photocatalytic activity. The
average oxygen evolution rate of BH400 is 1.4-, 1.7- and 1.9-fold
higher than that of CN–H, CH–B, and pristine g-C3N4, respectively (Figure S7, Supporting Information). This comparitive
results imply that boron dopants and nitrogen defects have the
synergetic effects on the greatly improved oxygen production
activity of g-C3N4. The gradual decrease in the oxygen evolution rate as the reaction prolonging (Figure 5e) is mainly due
to the light-shielding effect reducing optical absorption, with
the photoreduction of Ag+ on the surface of the catalyst.[32] This
is an inevitable phenomenon in photocatalytic water oxidation
as always observed in previous reports.[32–35] Then, to avoid the
optical shield effects of the photoreduced Ag particles, KIO3 was
used as electron scavenger to evaluate the photocatalytic stability of B