由于玻璃容器通常用于储存溶液和进行反应,因此人们通常认为它是惰性的,很少有人研究其对反应的影响。最近,美国普渡大学的R. Graham Co的英语翻译

由于玻璃容器通常用于储存溶液和进行反应,因此人们通常认为它是惰性的,很

由于玻璃容器通常用于储存溶液和进行反应,因此人们通常认为它是惰性的,很少有人研究其对反应的影响。最近,美国普渡大学的R. Graham Cooks教授等人提出了利用玻璃对Katritzky反应进行加速,并发现玻璃表面的硅醇基团能够促进Katritzky反应的去质子化,从而加速反应的进行。此外,作者还基于电喷雾质谱表征反应过程研究了玻璃对Katritzky反应动力学的影响,证明了界面(气/液界面和固/液界面)加速反应的原理。
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结果 (英语) 1: [复制]
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Since glass containers are usually used to store solutions and conduct reactions, they are generally considered to be inert, and few people have studied their effects on reactions. Recently, Professor R. Graham Cooks of Purdue University in the United States and others proposed the use of glass to accelerate the Katritzky reaction, and found that the silanol group on the glass surface can promote the deprotonation of the Katritzky reaction, thereby accelerating the progress of the reaction. In addition, the author also studied the effect of glass on the Katritzky reaction kinetics based on the electrospray mass spectrometry characterization of the reaction process, and proved the principle of the interface (gas/liquid interface and solid/liquid interface) to accelerate the reaction.
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结果 (英语) 2:[复制]
复制成功!
Because glass containers are commonly used to store solutions and react, they are often considered inert and few studies have studied their effects on reactions. Recently, R. Professor Graham Cooks et al. proposed using glass to accelerate the Katritzky reaction, and found that the silicol group on the glass surface can promote the denaturation of the Katritzky reaction, thus accelerating the reaction. In addition, the authors also studied the effects of glass on Katritzky reaction dynamics based on the electrospray mass spectrometry reaction process, demonstrating the principle of accelerating the reaction of the interface (gas/liquid interface and solid/liquid interface).
正在翻译中..
结果 (英语) 3:[复制]
复制成功!
Because glass container is usually used to store solution and carry out reaction, people usually think it is inert, and few people study its effect on reaction. Recently, Professor R. Graham cooks of Purdue University proposed to accelerate the katritzky reaction by using glass, and found that the silanol group on the surface of glass can promote the deprotonation of katritzky reaction, thus accelerating the reaction. In addition, the effect of glass on the kinetics of Katritzky reaction was studied by electrospray ionization mass spectrometry (ESI). The principle of accelerating reaction at interface (gas / liquid interface and solid / liquid interface) was demonstrated.<br>
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