Sustainable and robust superhydrophobic cotton fabrics were fabricated的简体中文翻译

Sustainable and robust superhydroph

Sustainable and robust superhydrophobic cotton fabrics were fabricated using a coating solution that consisted of a novel castor oil-based thiolated oligomer (CO−SH), octavinyl polyhedron oligomeric sesquiloxane (Octavinyl-POSS), and hydrophobic SiO2 (H−SiO2) nanoparticles, via spray deposition and UV-induced thiol-ene click chemistry. The novel CO−SH was synthesized through the thiol-ene click reaction of castor oil and 3-mercaptopropionic acid, following the esterification reaction with 2-mercaptoethanol. The wettability of the coated cotton fabrics was tunable by changing the concentration of H−SiO2 nanoparticles to ultimately obtain superhydrophobic coatings with self-cleaning properties. The highly robust superhydrophobic cotton fabric could resist at least 30 sandpaper abrasion cycles and 60 min ultrasound treatment without the loss of its superhydrophobicity. Meanwhile, the functional cotton fabric was capable of separating a variety of oil−water mixtures and emulsions with ultrahigh separation efficiency due to the excellent superhydrophobicity and superoleophilicity. The separation efficiency was maintained at a value above 99.990% even after 30 separation cycles. Therefore, the superhydrophobic fabric fabricated in this work can be practically employed as a highly efficient separation material in the management of oily water, which is to the benefit of the environment and human health.
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结果 (简体中文) 1: [复制]
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Sustainable and robust superhydrophobic cotton fabrics were fabricated using a coating solution that consisted of a novel castor oil-based thiolated oligomer (CO−SH), octavinyl polyhedron oligomeric sesquiloxane (Octavinyl-POSS), and hydrophobic SiO2 (H−SiO2) nanoparticles, via spray deposition and UV-induced thiol-ene click chemistry. The novel CO−SH was synthesized through the thiol-ene click reaction of castor oil and 3-mercaptopropionic acid, following the esterification reaction with 2-mercaptoethanol. The wettability of the coated cotton fabrics was tunable by changing the concentration of H−SiO2 nanoparticles to ultimately obtain superhydrophobic coatings with self-cleaning properties. The highly robust superhydrophobic cotton fabric could resist at least 30 sandpaper abrasion cycles and 60 min ultrasound treatment without the loss of its superhydrophobicity. Meanwhile, the functional cotton fabric was capable of separating a variety of oil−water mixtures and emulsions with ultrahigh separation efficiency due to the excellent superhydrophobicity and superoleophilicity. The separation efficiency was maintained at a value above 99.990% even after 30 separation cycles. Therefore, the superhydrophobic fabric fabricated in this work can be practically employed as a highly efficient separation material in the management of oily water, which is to the benefit of the environment and human health.
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结果 (简体中文) 2:[复制]
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可持续和健壮的超疏水棉织物是使用涂层溶液制造的,该溶液由新型脚轮油基硫化寡聚酰亚醇(CO_SH)、八溴二苯乙烯聚体素寡聚体糖(八氯乙烯-POSS)和疏水性SiO2(H+SiO2)纳米颗粒组成,通过喷雾沉积和UV诱导硫醇-ene咔嗒化学。新型CO_SH通过脚轮油和3-mercapto丙酮酸的thiol-ene咔嗒反应,在2-甲醇酯化反应后合成。涂层棉织物的湿润性可以通过改变 H_SiO2 纳米颗粒的浓度来调节,最终获得具有自清洁特性的超疏水涂层。高度坚固的超疏水棉织物可以抵抗至少30个砂纸磨损周期和60分钟的超声波治疗,而不会失去其超疏水性。同时,功能棉织物能够分离各种油水混合物和乳液,具有超高分离效率,由于优良的超水性性和超亲性。即使在 30 次分离循环后,分离效率仍保持在 99.990% 以上。因此,在这项工作中制造的超疏水织物实际上可以作为高效分离材料进行油性水管理,有利于环境和人类健康。
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结果 (简体中文) 3:[复制]
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利用一种新型蓖麻油基硫代低聚物(CO-SH)、八乙烯基多面体低聚物倍半氧烷(octavinyl POSS)和疏水性二氧化硅(H-SiO2)纳米粒子组成的涂层溶液,通过喷雾沉积和紫外诱导的巯基-烯键合化学方法,制备出了可持续且坚固的超疏水棉织物。以蓖麻油和3-巯基丙酸为原料,经2-巯基乙醇酯化反应,合成了新型CO-SH。通过改变H-SiO2纳米粒子的浓度,可调节涂层棉织物的润湿性,最终获得具有自清洁性能的超疏水涂层。高强度的超疏水棉织物在不丧失超疏水性的前提下,至少能抵抗30次砂纸磨损循环和60分钟的超声波处理。同时,功能性棉织物具有优异的超疏水性和超亲油性,能够分离多种油水混合物和乳化液,分离效率极高。即使经过30个分离周期,分离效率仍保持在99.990%以上。因此,本研究所制备的超疏水织物可以作为一种高效的油水分离材料,应用于含油污水的处理,有利于环境和人体健康。<br>
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