Oxygen is the enemy of wine. This is well understood. Leave the cork out of a bottle, or the bung out of a barrel, for long enough and even the most stalwart wine will sour and decay.And yet oxygen exposure during fermentation and élevage is essential to produce a stable and long-lasting wine. This is especially true for red wines, where its presence can help elongate tannins (which renders them more texturally smooth) and stabilize color, among other things. But as with ancient King Mithridates, who regularly consumed small amounts of poison to become immune to its fatal effects, wine must be fed oxygen in carefully controlled doses, lest the cure become the cancer.There are several ways to introduce oxygen to a fermenting or aging wine, and some of the more common methods are defined below. But first we must define oxidation, as it is a term with two meanings. In the wine industry, we think of oxidation as a flaw; a wine is “oxidized” when it tastes tired, either through faulty handling or old age. Sometimes, wines are deliberately oxidized, such as with Tawny Port or certain types of Sherry, but in general it is a quality to be avoided. Yet from a chemical perspective, oxidation is simply one half of a “redox” reaction (the other half being reduction), wherein electrons are exchanged in the production of stable molecular bonds. A compound or element is “oxidized” when it donates electrons to a bond, and is “reduced” when it gains electrons. Oxygen doesn’t actually need to be present for this to occur, but oxygen ions are by far the most famous oxidizers, as they need to donate two electrons to become stable (hence the reason they bond with two hydrogen ions to form water).
Oxygen is the enemy of wine. This is well understood. Leave the cork out of a bottle, or the bung out of a barrel, for long enough and even the most stalwart wine will sour and decay.<br><br>And yet oxygen exposure during fermentation and élevage is essential to produce a stable and long-lasting wine. This is especially true for red wines, where its presence can help elongate tannins (which renders them more texturally smooth) and stabilize color, among other things. But as with ancient King Mithridates, who regularly consumed small amounts of poison to become immune to its fatal effects, wine must be fed oxygen in carefully controlled doses, lest the cure become the cancer.<br><br>There are several ways to introduce oxygen to a fermenting or aging wine, and some of the more common methods are defined below. But first we must define oxidation, as it is a term with two meanings. In the wine industry, we think of oxidation as a flaw; a wine is “oxidized” when it tastes tired, either through faulty handling or old age. Sometimes, wines are deliberately oxidized, such as with Tawny Port or certain types of Sherry, but in general it is a quality to be avoided. Yet from a chemical perspective, oxidation is simply one half of a “redox” reaction (the other half being reduction), wherein electrons are exchanged in the production of stable molecular bonds. A compound or element is “oxidized” when it donates electrons to a bond, and is “reduced” when it gains electrons. Oxygen doesn’t actually need to be present for this to occur, but oxygen ions are by far the most famous oxidizers, as they need to donate two electrons to become stable (hence the reason they bond with two hydrogen ions to form water).
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