为了制备一种能快速、高效的检测EE2的电化学分子印迹传感器，通过水热法

In order to prepare a fast, efficient electrochemical detection of molecular imprinting EE2 sensors, platinum nanoparticles were synthesized by hydrothermal method, and then having a large specific surface area, high stability and high catalytic activity carboxylated high purity single wall carbon nanotubes mixed ultrasonic dispersion to obtain a COOH-SWCNTs-PtNPs composite materials, sol-gel method and then obtaining a molecularly imprinted polymer ethinylestradiol, a method of dispensing various materials supported on the glassy carbon electrode clean , thus preparing a novel molecularly imprinted electrochemical sensor ethinylestradiol. Scanning electron microscopy (SEM) and impedance (EIS) respectively modified electrode structure and electrochemical characterization, differential pulse stripping voltammetry (DPSV) and cyclic voltammetry (CV) was studied at different electrode EE2 electrochemical behavior influencing parameters, investigated and optimized substrate concentration, pH value, accumulation time, stirring speed. The results show that the oxidation peak current EE2 its concentration under optimal experimental conditions of 2.0 × 10 -7 ~ 2.0 × 10 -5 mol / good linear relationship, experiment measured between the lowest detection limit of L 2.5 × 10 -8 mol / L (S / N = 3). EE2 sensor for detecting the milk and water remaining in samples

In order to prepare an electrochemical molecular imprintsensor that can detect EE2 quickly and efficiently, platinum nanoparticles are synthesized by hydrothermal method, and then mixed with high-purity single-wall carbon nanotubes mixed with large surface area, strong stability and high catalytic activity, and obtain CO OH-SWCNTs-PtNPs composite materials, and then using the sol gel method to obtain the celenol molecular imprinting polymer, the method of drip coating to load a variety of materials on a clean glass carbon electrode, so as to produce a new type of celenol molecular imprint electrochemical sensor. The electrochemical behavior of EE2 on different electrodes was studied by using scanning electron mirror (SEM) and ACIS to shape and electrochemical characterization of the modified electrodes, and the electrochemical behavior of EE2 on different electrodes was studied by differential pulses, and the electrochemical behavior of eE2 was examined and optimized. The results showed that there was a good linear relationship between the oxidation peak current and its concentration of 2.0 x 10 -7 to 2.0 s 10 -5 mol/L under the optimal experimental conditions, and the minimum detection limit measured by the experiment was 2.5 x 10 -8 mol/L (S/N x 3). Use the sensor to detect residual EE2 in milk and water samples

In order to prepare an electrochemical molecularly imprinted sensor for rapid and efficient detection of EE2, platinum nanoparticles were synthesized by hydrothermal method. Then, the COOH-SWCNTs-PtNPs composite was obtained by ultrasonic dispersion with high specific surface area, strong stability and high catalytic activity of carboxyl high purity single-walled carbon nanotubes. Then, the molecularly imprinted polymer was obtained by sol-gel method. A new type of ethinylestradiol Molecularly Imprinted Electrochemical sensor was prepared by using drop coating method to load various materials on a clean glassy carbon electrode. Scanning electron microscopy (SEM) and alternating current impedance (EIS) were used to characterize the morphology and electrochemistry of the modified electrode. The electrochemical behavior of EE2 at different electrodes was studied by differential pulse stripping voltammetry (DPSV) and cyclic voltammetry (CV). The effects of the concentration of the bottom solution, pH value, enrichment time, stirring speed and other parameters were investigated and optimized. The results show that there is a good linear relationship between the oxidation peak current of EE2 and its concentration at 2.0 × 10-7 ~ 2.0 × 10-5 mol / L under the optimal experimental conditions, and the lowest detection limit is 2.5 × 10-8 mol / L (s / N = 3). The sensor is used to detect the residual EE2 in milk and water samples