A fuel cell, particularly one that must meet the challenging dynamic load of an automotive application, will undergo many rapid changes in load over the course of its lifetime.As the fuel cell cycles from high to low current, its cell potential will also vary, generally between 0.6 and 1.0 V. For cells operating with relatively pure hydrogen as a fuel, the anode will stay fairly close to the reversible hydrogen potential, due to the facile nature of the hydrogen oxidation reaction. This implies that the cathode experiences potential swings as cell potential changes to match variable power demands. The variation of the cathode potential will change several properties of the electrode materials, notably the degree of oxide coverage of both platinum and carbon, and the hydrophobicity of the surfaces.
A fuel cell, particularly one that must meet the challenging dynamic load of an automotive application, will undergo many rapid changes in load over the course of its lifetime.<br>As the fuel cell cycles from high to low current, its cell potential will also vary, generally between 0.6 and 1.0 V. For cells operating with relatively pure hydrogen as a fuel, the anode will stay fairly close to the reversible hydrogen potential, due to the facile nature of the hydrogen oxidation reaction. This implies that the cathode experiences potential swings as cell potential changes to match variable power demands. The variation of the cathode potential will change several properties of the electrode materials, notably the degree of oxide coverage of both platinum and carbon, and the hydrophobicity of the surfaces.
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